4.7 Article

Mechanism and application of surface-initiated ATRP in the presence of a Zn0 plate

Journal

POLYMER CHEMISTRY
Volume 11, Issue 44, Pages 7009-7014

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0py01233e

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Funding

  1. Brazilian agency Fundacao de Amparo a Pesquisa do Estado de Sao Paulo - FAPESP [2016/14493-7, 2017/22304-2]
  2. EMPA
  3. Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [17/22304-2] Funding Source: FAPESP

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Surface-initiated atom transfer radical polymerization in the presence of a Zn-0 plate (SI-Zn-0-ATRP) enables the rapid synthesis of chemically diverse polymer brushes from both planar inorganic supports, and fabrics made of natural fibers. This process enables the controlled formation of polymer-brush layers on a variety of substrates, without the need for either inert conditions or lengthy deoxygenation procedures of the reaction mixtures.

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