Journal
MOLECULES
Volume 25, Issue 22, Pages -Publisher
MDPI
DOI: 10.3390/molecules25225270
Keywords
non-proteinogenic amino acids; photo-mediated; C– H functionalization
Funding
- National Key R&D Program of China [2018YFA0901700]
- Fundamental Research Funds for the Central Universities [JUSRP12015]
- China Postdoctoral Science Foundation [2020M671329]
- Jiangsu Planned Projects for Postdoctoral Research Funds [2020Z383]
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Non-proteinogenic amino acids have attracted tremendous interest for their essential applications in the realm of biology and chemistry. Recently, rising C-H functionalization has been considered an alternative powerful method for the direct synthesis of non-proteinogenic amino acids. Meanwhile, photochemistry has become popular for its predominant advantages of mild conditions and conservation of energy. Therefore, C-H functionalization and photochemistry have been merged to synthesize diverse non-proteinogenic amino acids in a mild and environmentally friendly way. In this review, the recent developments in the photo-mediated C-H functionalization of proteinogenic amino acids derivatives for the rapid synthesis of versatile non-proteinogenic amino acids are presented. Moreover, postulated mechanisms are also described wherever needed.
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