Journal
NEW JOURNAL OF CHEMISTRY
Volume 44, Issue 46, Pages 20358-20366Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj04526h
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21671157, 21371143, 21501139]
Ask authors/readers for more resources
Due to the increasingly severe environmental pollution, there is an urgent need to find a new catalyst with high efficiency and stability for deep desulfurization of fuels. In this work, hybrid material based on vanadium-substituted Dawson type polyoxometalate and poly ionic liquid was facilely prepared and successfully loaded on different carbon materials to produce a supported catalyst for oxidative desulfurization. The test result shows that the catalyst P[C2VP]MoV/AC possesses high activity with the DBT conversion of 99.2%. At the same time, the catalyst with large specific surface area has more opportunities to react with sulfides and thus possesses high activity. According to the kinetic study, it is confirmed that the oxidation reaction of DBT follows first-order kinetics.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available