4.7 Article

Formation of uniformly sized metal oxide nanocuboids in the presence of precursor grains in an apolar medium

Journal

CRYSTENGCOMM
Volume 17, Issue 39, Pages 7477-7481

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce01257k

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Funding

  1. Advanced Low Carbon Technology Research and Development Program (ALCA) from Japan Science and Technology Agency (JST)
  2. Ministry of Education, Culture, Sports, Science and Technology [22107010, 2206, 15K14129]
  3. Grants-in-Aid for Scientific Research [15K14129] Funding Source: KAKEN

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Uniformly sized Mn3O4 nanocuboids were produced in the presence of tiny round grains similar to 3 nm in diameter covered with oleic acid in toluene. The formation of rectangular nanocrystals surrounded with {100} and (001) faces is attributable to the oriented attachment of precursor grains in an apolar medium in which the metal and hydroxide ions are insoluble.

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