Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 47, Pages 25094-25100Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta10024b
Keywords
-
Funding
- National Science Fund for Distinguished Young Scholars [21825106]
- National Natural Science Foundation of China [21905254, 21671175]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
- Program for Innovative Research Team (in Science and Technology) in Universities of Henan Province [19IRTSTHN022]
- Zhengzhou University
Ask authors/readers for more resources
Herein, we report a designed binuclear Cu-salphen covalent organic framework (COF) that can be exfoliated into ultrathin nanosheets (denoted as Cu-salphen-HDCOF-NSs) for photoactive catalytic hydrogen evolution. Its conjugated porous architecture, coupled with high loading of isolated Cu active sites, can not only efficiently increase the access of photogenerated charge to the surface redox reaction centers, but can also prohibit the recombination of photoexcitons. As a result, Cu-salphen-HDCOF-NSs exhibit a remarkable hydrogen evolution rate of 36.99 mmol g(-1) h(-1) under visible-light irradiation, which is far higher than those of reported Pt-assisted COF photocatalytic systems. This finding provides new insight into the design of COF catalysts for efficient artificial photocatalysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available