4.5 Article

CdAl mixed metal oxides prepared by calcination of CdAl layered double hydroxides: Synthesis and properties for humidity sensing

Journal

SOLID STATE SCIENCES
Volume 109, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solidstatesciences.2020.106393

Keywords

Humidity sensing properties; CdO/CdAl2O4 composites; Cd/Al layered double hydroxide

Funding

  1. National Natural Science Foundation of China [NSFC 21627813, 51472021]
  2. Fundamental Research Funds for the Central Universities [12060093063, XK1802-6]

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In this work, CdAl mixed metal oxides (CdAl-MMOs), CdO/CdAl2O4 composites, were prepared by calcination of sodium dodecyl sulfonate (SDS) intercalated CdAl layered double hydroxide (CdAl-LDH) at different temperature, which was synthesized by traditional hydrothermal synthesis. The CdAl-MMOs were investigated at room temperature, which shows good humidity-sensing performance. Especially, the one calcined at 500 degrees C (CdAlMMO-500) shows good linearity, small hysteresis, high humidity sensitivity as well as satisfactory response and recovery time. In addition, the composites CdO/CdAl2O4 have improved the humidity-sensing performances as compared to the one obtained by calcination of the blending inorganic salts. The experimental results further demonstrate that the approach of calcination LDH precursor can be generalized as an effective way of making mixed metal oxides (MMOs) with homogeneous dispersion between metal elements and thus specific properties.

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