4.7 Article

One-pot synthesis of Zn-doped SnO2 nanosheet-based hierarchical architectures as a glycol gas sensor and photocatalyst

Journal

CRYSTENGCOMM
Volume 17, Issue 23, Pages 4394-4401

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce00546a

Keywords

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Funding

  1. Taishan Scholar [TSHW20120210]
  2. National Natural Science Foundation of China [11304120, 21322106, 51472097]
  3. Ministry of Science and Technology of China [2015CB932600]
  4. Encouragement Foundation for Excellent Middle-Aged and Young Scientist of Shandong Province [BS2012CL005, BS2013CL020, BS2014CL012]

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Zn-doped SnO2 hierarchical architectures (ZSHAs) with controllable size have been prepared using a facile hydrothermal method, which are composed of two dimensional (2D) nanosheets with a thickness of about 40 nm. The properties of ZSHAs have been explored by gas sensing and photocatalysis testing. A sensor response (S = R-a/R-g) of 43 can be achieved at 100 ppm glycol, and the detection limit can reach down to the 5 ppm level with a response of about 5, combined with a low operating temperature of 240 degrees C, suggesting a promising application of ZSHAs in glycol gas sensing. Besides, the photocatalytic activities of ZSHAs have been evaluated by the degradation measurement of methylene blue (MB), methylene orange (MO), and rhodamine B (RhB). As a result, the ZSHAs demonstrate a much higher selectivity on the degradation of MB (91%) than that of MO (40%) and RhB (60%) in 60 min of measurement.

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