Journal
CRYSTAL GROWTH & DESIGN
Volume 15, Issue 8, Pages 3847-3852Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.5b00473
Keywords
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Funding
- National Natural Science Foundation of China [21207018, 21273033, 21203024]
- Fujian Science and Technology Department [2014J06003, 2014H6007]
- Recruitment Program of Global Young Experts
- Program for New Century Excellent Talents in University [NCET-10-0108]
- Award MinJiang Scholar Program in Fujian Province
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A microporous metal-organic framework (FJU-12), {[Cd-12(Trz)(8)(DMF)(2)(H2O)(4)](BDC)(9)}.2(Me2NH2).4DMF.16H(2)O (Trz = 1,2,4-triazole, BDC = terephthalic acid, DMF = N,N-dimethylformamide), was rationally constructed using unprecedented lantern-like 1,2,4-triazole-based dodecanuclear metal coordination cages as supermolecular building blocks. After activation, FJU-12a exhibits highly selective adsorption of C-2 compound/CH4 mixtures and efficient sensing of nitrobenzene (NB). The selectivity (79.7) of C2H2/CH4 is comparable to the most selective Cu-TDPAT (82, TDPAT = 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine).
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