Journal
CRYSTAL GROWTH & DESIGN
Volume 15, Issue 5, Pages 2253-2259Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.5b00024
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Funding
- 973 Program of China [2014CB845600]
- NSF of China [21290171, 21421001]
- MOE Innovation Team of China [IRT13022]
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The reaction of polydentate ligand Bis-tris propane {(CH2OH)(3)CNH-(CH2)(3)NHC(CH2OH)(3)} with Ln(NO3)(3)-6H(2)O and Fe3O precursor resulted in the formation of a series of Fe(6)Ln(2) nanoclusters. Magnetic measurements indicate that the Fe-6 core exhibits ferrimagnetic behavior, and slow magnetic relaxation was observed in Fe6Dy2 and Fe6Tb2.
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