Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 98, Pages 15462-15465Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06038k
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Funding
- CSIR, India [31/6(422)/2017-EMR-I]
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Hypervalent iodonium ylides expeditiously generate carbenes which undergo domino intermolecular C-H activation followed by intramolecular condensation in the presence of N-methoxybenzamide as a starting material and a Rh(iii)-catalyst to afford dihydrophenanthridines. KIE studies and DFT calculations were performed to substantiate the mechanistic pathway. To extend the synthetic utilisation, fluorescent pyranoisocoumarins were achieved by using Rh(iii)-catalyzed peri-C-H/O-H activation/annulation reactions.
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