Journal
CRYSTAL GROWTH & DESIGN
Volume 15, Issue 4, Pages 1568-1571Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.5b00209
Keywords
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Funding
- 973 program [2011CB932504, 2012CB821705]
- NSFC [21221001, 21103189]
- Chunmiao Project of Haixi Institute of Chinese Academy of Sciences [CMZX-2015-001]
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Presented here is an unusual microporous metal-organic framework (FIR-30) integrating helical channels, intrinsical chirality, and permanent porosity. The structure of FIR-30 containing three types of cages has two interpenetrating helical channel systems with opposite handedness, which can be considered a surface with the same topology as gyroid, and the generation of chirality is related with the intrinsically chiral topology of FIR-30. The results provide new insight toward the construction of chiral MOFs with helical channels.
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