Journal
CRYSTAL GROWTH & DESIGN
Volume 15, Issue 4, Pages 1871-1875Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.5b00039
Keywords
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Funding
- Deanship of Scientific Research (DSR), King Abdulaziz University [70-130-35-HiCi]
- KAU
- Welch Foundation [AX-1730]
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Two hydrogen-bonded organic frameworks (HOFs) of the melamine (MA), MA-1-H2O and MA-2-DMF, have been crystallized in H2O and DMF (N,N-Dimethylformamide), respectively. Structurally, MA-1-H2O and MA-2-DMF are condensed and porous, respectively. The porous MA-2-DMF sustains the porous feature under the solvent exchange by acetone, dichloromethane (CH2Cl2), and toluene, while it transforms into the condensed one under methanol (MeOH) and ethanol (EtOH). Furthermore, MA-2-DMF and MA-2-Toluene can undergo reversible single crystal-single crystal transformation with retention of the porous hydrogen-bonded organic frameworks.
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