Journal
CRYSTAL GROWTH & DESIGN
Volume 15, Issue 2, Pages 538-541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg501571u
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Funding
- National Science Foundation [LRM DMR-1408834]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1408834] Funding Source: National Science Foundation
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Face-to-face perfluorophenylperfluorophenyl interactions (C6F5 center dot center dot center dot C6F5) are achieved in a disilver metalorganic complex. The C6F5 center dot center dot center dot C6F5 interactions along with argentophilic forces support trans-pentafluorostilbazole to undergo a head-to-head [2 + 2] photodimerization to form a cyclobutane that sustains a fluorinated two-dimensional metalorganic framework.
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