Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 40, Issue 11, Pages 3620-3632Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc202006068
Keywords
decatungstate; hydrogen atom transfer (HAT); photocatalysis; radical; C-H functionalization
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Funding
- National Natural Science Foundation of China [21971224]
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In recent years, decatungstate [W10O32](4-) as a catalyst has attracted much attention in the field of photocatalytic organic synthesis. With the catalysis of decatungstate, the C-H bond of substrate can be converted into the corresponding radical via a hydrogen atom transfer (HAT) progress under light irradiation. In this review, we summarized the recent advances of the application of decatungstate as a photocatalyst for the C-H functionalization to construct C-C, C-N, C-F bonds.
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