Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 86, Pages 13145-13148Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05630h
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Funding
- JSPS KAKENHI [19K07000]
- Grants-in-Aid for Scientific Research [19K07000] Funding Source: KAKEN
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The first successful example of the direct synthesis of Weinreb amides using catalytic hydroxy-directed dehydrative amidation of carboxylic acids using the diboronic acid anhydride catalyst is described. The methodology is applicable to the concise syntheses of eight alpha -hydroxyketone natural products, namely, sattabacin, 4-hydroxy sattabacin, kurasoins A and B, soraphinols A and B, and circumcins B and C.
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