4.7 Article

Water-soluble BDPA radicals with improved persistence

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 86, Pages 13121-13124

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04920d

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Funding

  1. Icelandic Research Fund [163393-052]
  2. University of Iceland Research Fund

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1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble in polar solvents and are highly persistent, with 5-20-fold lower initial rates of degradation than BDPA.

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