Journal
DALTON TRANSACTIONS
Volume 49, Issue 48, Pages 17547-17551Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt03938a
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Funding
- RUDN University Strategic Academic Leadership Program
- Spanish MICIU/AEI [CTQ2017-85821-R]
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A new coordination polymer [Hg(L-I)I](n) (1) and a new discrete coordination complex [Hg(HLII)I-2] (2) are synthesized and X-ray characterized. The existence of positive pi-holes at the spodium atoms in both compounds is evidenced by DFT calculations. In 1, a Hg-S semicoordination bond and a Hg center dot center dot center dot I spodium bond are formed at opposite sides of the pi-hole. In 2, two different Hg center dot center dot center dot I spodium bonds are formed at both sides of the pi-hole. This is the first study describing structure-guiding pi-hole spodium bonding.
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