Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 47, Pages 19844-19849Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c09949
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Funding
- National Natural Science Foundation of China [91856104, 21871145, 21672107]
- China Postdoctoral Science Foundation [2018M641625]
- Tianjin Applied Basic Research Project and Cutting-Edge Technology Research Plan [19JCZDJC37900]
- Fundamental Research Funds for the Central Universities, Nankai University [63191601]
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A carbamoyl fluoride-enabled enantioselective Ni-catalyzed carbocarbamoylation of unactivated alkenes was developed, providing a broad range of chiral gamma-lactams bearing an all-carbon quaternary center in 45-96% yield and 38-97% ee.
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