Journal
ORGANIC LETTERS
Volume 22, Issue 21, Pages 8643-8647Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03248
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Funding
- NFS of China [21801188]
- Shanghai Pujiang Program
- 1000 Youth Talents Plan
- Tongji University
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The first catalytic strategy to harness a new chloromethane radical from dichloromethane under dual Ni/photoredox catalytic conditions has been developed. Compared with traditional two-electron reductive process associated with metallic reductants, this method via a single-electron approach can proceed under exceptionally mild conditions (visible light, ambient temperature, no strong base) and exhibits complementary reactivity patterns. It affords a broad scope of many functional groups, including alkenyl, which suffers cyclopropanation in previous routes. The diarylmethane-d2 compounds can be readily available with this transformation.
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