Journal
ACS NANO
Volume 14, Issue 11, Pages 16140-16155Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.0c08671
Keywords
MXenes; 2D material; hybrid material; electrocatalysis; hydrogen evolution; long-term stability; high current density
Categories
Funding
- Singapore National Research Foundation [NRF-NRFF2017-04]
Ask authors/readers for more resources
The development of highly efficient and durable earth-abundant hydrogen evolution reaction (HER) catalysts is crucial for the extensive implementation of the hydrogen economy. Members of the 2D MXenes family, particularly Mo2CTx, have recently been identified as promising HER catalysts. However, their inherent oxidative instability in air and aqueous electrolyte solutions is hindering their widespread use. Herein, we present a simple and scalable method to circumvent adventitious oxidation in Mo2CTx MXenes via in situ sulfidation to form a Mo2CTx/2H-MoS2 nanohybrid. The intimate epitaxial coupling at the Mo2CTx/2H-MoS2 nanohybrid interface afforded superior HER activities, requiring only 119 or 182 mV overpotential to yield -10 or -100 mA cm(geom)(-2) current densities, respectively. Density functional theory calculations reveal strongest interfacial adhesion was found within the nanohybrid structure as compared to the physisorbed nanohybrid, and the possibility to tune the HER overpotential through manipulating the extent of MXene sulfidation. Critically, the presence of 2H-MoS2 suppresses further oxidation of the MXene layer, enabling the nanohybrid to sustain industrially relevant current densities of over -450 mA cm(geom)(-2) with exceptional durability. Less than 30 mV overpotential degradation was observed after 10 continuous days of electrolysis at a fixed -10 mA cm(geom)(-2) current density or 100,000 successive cyclic voltammetry cycles. The exceptional HER durability of the Mo2CTx/2H-MoS2 nanohybrid presents a major step forward to realize practical implementation of MXenes as noble metal free catalysts for broad-based applications in water splitting and energy conversion.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available