4.7 Article

Critical behavior of polycrystalline Pr0.7Ca0.1Sr0.2MnO3 exhibiting the crossover of first and second order magnetic phase transitions

Journal

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
Volume 9, Issue 6, Pages 12747-12755

Publisher

ELSEVIER
DOI: 10.1016/j.jmrt.2020.09.013

Keywords

Manganites; Phase transformation; Critical exponents; Magnetic interactions; Tricritical mean field

Funding

  1. Ministry of Science and Technology in Thai Nguyen University of Sciences, Thai Nguyen University [B2019-TNA-01.VL]
  2. Vietnam National Foundation for Science and Technology Development (NAFOSTED) [103.02-2019.42]
  3. Vietnam Academy of Science and Technology [QTRU01.06/20-21, 20-58-54006]
  4. Russian Foundation for Basic Research [QTRU01.06/20-21, 20-58-54006]
  5. National Research Foundation of Korea [2020R1A2C1008115]
  6. National Research Foundation of Korea [2020R1A2C1008115] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A polycrystalline ceramic of Pr0.7Ca0.1Sr0.2MnO3 was prosperously synthesized by the solid state reaction method. The M(T, H) data measured at different temperatures in applied magnetic fields H = 0-30 kOe showed that the material has a ferromagnetic-paramagnetic phase transition and exhibits the crossover of the first and second order magnetic phase transitions. Above Curie temperature (T-C), the chi(-1)(T) curve witnesses a downturn in the paramagnetic region, suggesting an appearance of the Griffiths phase. Using the modified Arrott plots and the Kouvel-Fisher methods, we have identified a set of the critical parameters (T-C, beta, gamma, and delta) for Pr0.7Ca0.1Sr0.2MnO3 compound. The results are found to be T-C = 205.5 + 0.1 K, beta = 0.191 + 0.010, gamma = 0.856 + 0.016 and delta = 5.649 + 0.030. It can be seen that the values of the exponents beta, gamma, and delta are quite close to the exponents of the tricritical mean field model. Additionally, they satisfy the scaling theory well, proving their reliability. Based on obtained results, we suggest that the ferromagnetic-paramagnetic transition in Pr0.7Ca0.1Sr0.2MnO3 compound is located at a crossover of the first and second order transformations. (C) 2020 The Author(s). Published by Elsevier B.V.

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