Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 96, Pages 15133-15136Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05989g
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Funding
- NSF [21435003, 21521004, 21820102006, 91856118]
- MOE of China [IRT13036]
- SAMP
- T project of Xiamen [3502Z20203025]
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We propose using the formation of coordination polymers of Ag+ to probe differences between the perfluorinated alkyl chain and the alkyl chain by deriving a thiol ligand, N-(perfluoroalkanoyl)cysteine. Rapid formation in EtOH of P-/M-helical nanofibrils of high thermostability was found for N-(perfluorooctanoyl)-L-/D-cysteine ethyl esters at the mu M level uponmixing with Ag+, but not for the octanoyl counterpart. This difference was also observed in terms of circular dichroism-enantiomeric excess dependence.
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