Adsorption of Reactive Black 5 Dye from Aqueous Solutions by Carbon Nanotubes and its Electrochemical Regeneration Process

Removal of Reactive Black 5 (RB5) dye from aqueous solutions was investigated by adsorption onto Multi-walled Carbon Nanotubes (MWCNTs) and Single-walled Carbon Nanotubes (SWCNTs). A Taguchi orthogonal design including pH, initial RB5 concentration, contact time, and CNTs dose, was used in 16 experiments. The results showed that all four factors were statistically significant, and the optimum conditions for both adsorbents were as follows: pH of 3, adsorbent dose of 1000 mg/L, RB5 concentrations of 25 mg/L, and contact time of 60 min. An equilibrium study by Isotherm Fitting Tool (ISOFIT) software showed that Langmuir isotherm provided the best fit for RB5 adsorption by CNTs. The maximum predicted adsorption capacities for the dye were obtained as 231.84 and 829.20 mg/g byMWCNTs and SWCNTs, respectively. The results also indicated that the adsorption capacity of SWCNTs was about 1.21 folds higher than that of MWCNTs. Studies of electrochemical regeneration were conducted, and the results demonstrated that RB5-loaded MWCNTs and SWCNTs could be regenerated (86.5% and 77.3%, respectively) using the electrochemical process. Adsorbent regeneration was mostly due to the degradation of the dye by the attack of active species such as chlorate, H2O2, and, center dot OH, which were generated by the electrochemical oxidation process with Ti/RuO2-IrO2-TiO2 anodes. The results of Gas Chromatography-Mass Spectrometry (GC-MS) analysis showed that acetic acid, 3-chlorobenzenesulfonamide, and 1,2-benzenedicarboxylic acid were produced after adsorbent regeneration by the electrochemical process in the solution of regeneration. The adsorption and regeneration cycles showed that the electrochemical process with Ti/RuO2-IrO2-TiO2 and graphite is a good alternative method for the regeneration of CNTs and simultaneous degradation of the dye.