Ices on Mercury: Chemistry of volatiles in permanently cold areas of Mercury's north polar region

Observations by the MESSENGER spacecraft during its flyby and orbital observations of Mercury in 2008-2015 indicated the presence of cold icy materials hiding in permanently-shadowed craters in Mercury's north polar region. These icy condensed volatiles are thought to be composed of water ice and frozen organics that can persist over long geologic timescales and evolve under the influence of the Mercury space environment. Polar ices never see solar photons because at such high latitudes, sunlight cannot reach over the crater rims. The craters maintain a permanently cold environment for the ices to persist. However, the magnetosphere will supply a beam of ions and electrons that can reach the frozen volatiles and induce ice chemistry. Mercury's magnetic field contains magnetic cusps, areas of focused field lines containing trapped magnetospheric charged particles that will be funneled onto the Mercury surface at very high latitudes. This magnetic highway will act to direct energetic protons, ions and electrons directly onto the polar ices. The radiation processing of the ices could convert them into higher-order organics and dark refractory materials whose spectral characteristics are consistent with low-albedo materials observed by MESSENGER Laser Altimeter (MLA) and RADAR instruments. Galactic cosmic rays (GCR), scattered UV light and solar energetic particles (SEP) also supply energy for ice processing. Cometary impacts will deposit H2O, CH4, CO2 and NH3 raw materials onto Mercury's surface which will migrate to the poles and be converted to more complex C-H-N-O-S-containing molecules such as aldehydes, amines, alcohols, cyanates, ketones, hydroxides, carbon oxides and suboxides, organic acids and others. Based on lab experiments in the literature, possible specific compounds produced may be: H2CO, HCOOH, CH3OH, HCO, H2CO3, CH3C(O)CH3, C2O, CxO, C3O2, CxOy, CH3CHO, CH3OCH2CH2OCH3, C2H6, CxHy, NO2, HNO2, HNO3, NH2OH, HNO, N2H2, N-3, HCN, Na2O, NaOH, CH3NH2, SO, SO2, SO3, OCS, H2S, CH3SH, even BxHy. Three types of radiation processing mechanisms may be at work in the ices: (1) Impactfdissociation, (2) Ion implantation and (3) Nuclear recoil (hot atom chemistry). Magnetospheric energy sources dominate the radiation effects. Total energy fluxes of photons, SEPs and GCRs are all around two or more orders of magnitude less than the fluxes from magnetospheric energy sources (in the focused cusp particles). However, SEPs and GCRs cause chemical processing at greater depths than other particles leading to thicker organic layers. Processing of polar volatiles on Mercury would be somewhat different from that on the Moon because Mercury has a magnetic field while the Moon does not. The channeled flux of charged particles through these magnetospheric cusps is a chemical processing mechanism unique to Mercury as compared to other airless bodies. (C) 2016 Elsevier Inc. All rights reserved.