Journal
HIGH PERFORMANCE POLYMERS
Volume 29, Issue 6, Pages 646-650Publisher
SAGE PUBLICATIONS LTD
DOI: 10.1177/0954008317696565
Keywords
Hyperbranched polyimide; TEMPO; aerobic oxidation; heterogeneous catalyst; recyclable
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Funding
- JSPS KAKENHI [26870183]
- Grants-in-Aid for Scientific Research [26870183] Funding Source: KAKEN
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Hyperbranched polyimide functionalized with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied as a heterogeneous catalyst for the aerobic oxidation of benzyl alcohol. The catalyst material was synthesized by an A(2) + B-3 polymerization of pyromellitic dianhydride and 1,3,5-tris(4-aminophenyl)benzene followed by an end-capping reaction with 4-amino-TEMPO. Selective aerobic oxidation of benzyl alcohol to benzaldehyde has been demonstrated using the prepared materials as a catalyst. The recyclability of these materials has been confirmed by recycling tests using the catalyst collected by filtration.
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