4.5 Article

Reduction of the acidity and peroxide numbers of tengkawang butter (Shorea stenoptera) using thermal and acid activated bentonites

Journal

HELIYON
Volume 6, Issue 12, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.heliyon.2020.e05742

Keywords

Agricultural engineering; Analytical chemistry; Chemical engineering; Natural product; Natural product chemistry; Acidity; Bleaching; Fatty acid; Peroxide number; Tengkawang butter

Funding

  1. Hibah Program Menuju Doktor Mahasiswa Unggul (PMDSU) 2020 [NKB-442/UN2.RST/HKP.05.00/202]
  2. Universitas Indonesia through PUTI Doktor [NKB-688/UN2.RST/HKP.05.00/2020]

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Tengkawang fat (Shorea stenoptera), from an indigenous plant of the Kalimantan forest, has excellent potential as an alternative source of vegetable fat because it has a high level of fatty acids composition. Activated natural bentonite can be used as a bleaching agent to improve the quality of tengkawang fat. This research aims to reduce the acidity, peroxide number values and identify the physicochemical properties (fatty acid composition, nutrients, and thermal) of tengkawang butter. Initially, tengkawang samples from Nanga Yen and Sintang were pretreated using the degumming process with 1% phosphoric acid and the neutralization process with a 1 M NaOH 10% w/w solution. The results show that the acidity (mg NaOH/g) of the tengkawang fat samples was reduced from 11.00 to 3.36 when using bentonite activated at 200 degrees C. The bentonite activated with 0.5 M HCl reduced the acidity to 3.61. The peroxide number (meq O-2/kg) of the tengkawang fat samples was reduced from 9.45 to 4.84 and 3.47 by bleaching with thermal-activated and acid-activated bentonites, respectively. Peroxide value correlates with beta-carotene content. The smaller of the beta-carotene content, the smaller the peroxide value. The acidity, peroxide number, and iodine number values from tengkawang fat after treatment adhere to the SNI 2903: 2016 standard. The main content of fatty acids in tengkawang fat is palmitic acid, stearic acid, and oleic acid. These results show that both products are suitable for the food industry in terms of the acid and peroxide numbers. The application of this research results will assist local people in increasing the economic value of the product from tengkawang plant, which is an indigenous plant from Kalimantan.

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