4.6 Review

Magnetic Solid-Phase Extraction Based on Modified Ferum Oxides for Enrichment, Preconcentration, and Isolation of Pesticides and Selected Pollutants

Journal

CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
Volume 45, Issue 3, Pages 270-287

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/10408347.2014.938148

Keywords

pesticides; organic; biological species; magnetic solid phase extraction; modified Fe3O4; inorganic; magnetic nanoparticles

Funding

  1. Ministry of Education Malaysia through Research University Grants [04H22, 10J43]
  2. Ministry of Education Malaysia for the Fundamental Research Grant Scheme (FRGS) grant [4F307]
  3. UTM

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Recently, a simple, rapid, high-efficiency, selective, and sensitive method for isolation, preconcentration, and enrichment of analytes has been developed. This new method of sample handling is based on ferum oxides as magnetic nanoparticles (MNPs) and has been used for magnetic solid-phase extraction (MSPE) of various analytes from various matrices. This review focuses on the applications of modified ferum oxides, especially modified Fe3O4 MNPs, as MSPE adsorbent for pesticide isolation from various matrices. Further perspectives on MSPE based on modified Fe3O4 for inorganic metal ions, organic compounds, and biological species from water samples are also presented. Ferum(III) oxide MNPs (Fe2O3) are also highlighted.

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