4.8 Article

MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditions

Journal

GREEN CHEMISTRY
Volume 19, Issue 7, Pages 1619-1623

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc00027h

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Funding

  1. Ministry of Science, ICT & Future Planning [2012 M3C1A1054497]
  2. Internal Research Program of Korea Institute of Industrial Technology [PEO 17250]
  3. National Research Council of Science & Technology (NST), Republic of Korea [EO170025] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A new class of MnCo2O4 spinel supported Ru catalyst, Ru/MnCo2O4, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo2O4 having both Lewis and Bronsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.

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