Journal
GREEN CHEMISTRY
Volume 19, Issue 13, Pages 2973-2979Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc00693d
Keywords
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Funding
- Federal Ministry of Education and Research (Bundesministerium fur Bildung und Forschung, BMBF) [03SF0498]
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The mechanochemical Suzuki polycondensation constitutes a sustainable alternative to classical solvent-based polymerization reactions for poly(phenylene)s. In order to establish a basic understanding of the process, important reaction parameters like the milling material, halide type and polymerization system are investigated. Under optimized conditions, we have been able to synthesize linear polymers with an outstanding degree of polymerization of 164, in a ligand free environment - in as little as 30 minutes. In addition, the developed principle is broadened to a hyperbranched system with high temperature resistance and high yields in short reaction times.
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