Journal
GREEN CHEMISTRY
Volume 19, Issue 3, Pages 634-637Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02908f
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Funding
- National Thousand Young Talents Program [YC0130518]
- Shanghai Pujiang Program [15PJ1401500]
- Fundamental Research Funds for the Central Universities [WY1514052]
- Opening Project of State Key Laboratory of Bio-organic and Natural Products Chemistry [Y100-D-1501]
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A practical and efficient synthesis of chloro(organophosphine) gold(I) complexes is reported. Employment of 4,4'-dihydroxydiphenyl sulfide as a safe and non-irritating reductant is highlighted for the generation of Au(I)-S intermediates, which could be trapped by mono-and bidentate phosphine ligands to provide organophosphine gold(I) complexes. The utility of the present method is further demonstrated by the synthesis of the antiarthritic drug auranofin.
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