Journal
GREEN CHEMISTRY
Volume 19, Issue 9, Pages 2118-2122Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc00602k
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Funding
- Excellence Initiative of the German federal and state governments
- Fonds der Chemischen Industrie
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Diazo acetonitrile has long been neglected despite its high value in organic synthesis due to a high risk of explosions. Herein, we report our efforts towards the transient and safe generation of this diazo compound, its applications in iron catalyzed cyclopropanation and cyclopropenation reactions and the gram-scale synthesis of cyclopropyl nitriles.
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