4.8 Article

Organic sponge photocatalysis

Journal

GREEN CHEMISTRY
Volume 19, Issue 13, Pages 2925-2930

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc03558b

Keywords

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Funding

  1. National Natural Science Foundation of China [21402124, 21404072, 21605104]
  2. Training Foundation for Outstanding Young Teachers in Higher Education Institutions of Guangdong [YQ2015145]
  3. Shenzhen Science and Technology Foundation [JCYJ20150324141711702, JCYJ20150324140036849, JCYJ20140418182819116]
  4. Natural Science Foundation of SZU [827000038, 201446, 201447, 201519]

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The successfully developed polydimethylsiloxane (PDMS, a green and highly transparent polymer material) sponge photocatalyst can catalyze cross-dehydrogenative coupling (CDC) of tertiary amines and various nucleophiles with high efficiency and reusability under visible light irradiation. Through an easy-to-build continuous flow reactor, the sponge photocatalytic reaction can be facilely scaled up.

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