Journal
GREEN CHEMISTRY
Volume 19, Issue 7, Pages 1613-1618Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc03521c
Keywords
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Funding
- Natural Science Foundation of China [21372174, 21542015, 21672157]
- PAPD
- Soochow University
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A novel and facile metal-free method for the green synthesis of 1,2,4-selenadiazol-5-amine derivatives through the aerobic radical-cascade multi-component reactions of isocyanides, selenium powder and imidamides is reported herein. O-2 in the air was employed as the green oxidant to achieve the cycloaddition with the generation of H2O as the sole by-product. It also features good functional group compatibility and broad substrate scope. In addition, this method was successfully applied to the functionalization of biologically active molecules.
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