Journal
GREEN CHEMISTRY
Volume 19, Issue 6, Pages 1420-1424Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02619b
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The application of Reformatsky and Blaise reactions for the preparation of a diverse set of valuable intermediates and heterocycles in a one-pot protocol is described. To achieve this goal, a greener activation protocol for zinc in flow conditions has been developed to introduce this metal efficiently into alpha-bromoacetates. The organozinc compounds were added to a diverse set of ketones and nitriles to obtain a wide range of functional groups and heterocyclic systems.
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