Journal
GREEN CHEMISTRY
Volume 19, Issue 20, Pages 4811-4815Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc01993a
Keywords
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Funding
- FCT (Fundacao para a Ciencia e a Tecnologia, Portugal) [UID/QUI/00100/2013, PTDC/QEQ-ERQ/1648/2014]
- Fundação para a Ciência e a Tecnologia [PTDC/QEQ-ERQ/1648/2014] Funding Source: FCT
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The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 x 10(3)) directly from carbon dioxide is achieved by using H-2 and the iron(II) scorpionate catalyst [FeCl2{kappa(3)- HC(pz)(3)}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.
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