Journal
GREEN CHEMISTRY
Volume 19, Issue 15, Pages 3530-3534Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc01467h
Keywords
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Funding
- National Natural Science Foundation of China [21402028]
- Fuzhou University [510269]
- Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University [52003426]
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We developed a photoinduced radical fragmentation and rearrangement of vinyl tosylates that enables efficient formation of beta-ketosulfones. This process is based on the photoinitiated homolysis of vinyl tosylate to release a sulfinyl radical from the tosyl group and the subsequent addition of a sulfinyl radical to another vinyl tosylate to form the desired beta-ketosulfones. This simple protocol features a broad scope with both aromatic and aliphatic substrates, convenient reagents and operating systems.
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