Journal
GREEN CHEMISTRY
Volume 19, Issue 18, Pages 4299-4304Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc01588g
Keywords
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Funding
- Spanish MINECO [MAT2013-40950-R, CTQ2014-52956-C3-1-R, MAT2016-78155C2-1-R]
- Gobierno del Principado de Asturias [GRUPIN14-060, GRUPIN14-078]
- Severo Ochoa PhD grant [BP-14-029]
- FEDER
- Ministry of Education and Science of the Russian Federation [4.1157.2017/PP, 4.9722.2017/8.9]
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The unprecedented ability of g-C3N4 to chemoselectively photo-oxidise the methyl group of 2-(4-methylphenoxy) ethanol instead of the easily oxidised oxyethanol fragment has been demonstrated. When g-C3N4 is treated with H2O2, its selectivity enhances due to the blocking of surface sites responsible for the adsorption and the subsequent oxidation of the oxyethanol substituent.
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