4.8 Article

Visible-light-driven conversion of CO2 from air to CO using an ionic liquid and a conjugated polymer

Journal

GREEN CHEMISTRY
Volume 19, Issue 24, Pages 5777-5781

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc02346d

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Funding

  1. National Natural Science Foundation of China [21533011, 21673256]
  2. Chinese Academy of Sciences [QYZDY-SSW-SLH013-2]

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A metal-free and highly efficient catalytic system involving a task-specific ionic liquid, [P-4444][p-2-O], and a pyrene-based conjugated polymer was developed for direct CO2 capture from air and its further photoreduction to CO under visible light irradiation, affording a CO production rate of 47.37 mu mol g(-1) h(-1) with a selectivity of 98.3%.

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