4.7 Article

Distribution of Dissolved Zinc in the Western and Central Subarctic North Pacific

Journal

GLOBAL BIOGEOCHEMICAL CYCLES
Volume 31, Issue 9, Pages 1454-1468

Publisher

AMER GEOPHYSICAL UNION
DOI: 10.1002/2017GB005711

Keywords

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Funding

  1. Monkasho (Ministry of Education, Culture, Sports, Science and Technology: MEXT) [23253001, 16H02701, JPH05820]
  2. Grants-in-Aid for Scientific Research [15H05820, 16H02701] Funding Source: KAKEN

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We investigated the biogeochemical cycling of dissolved zinc (Zn) in the western and central subarctic North Pacific during the GEOTRACES GP 02 cruise. The relationship between dissolved Zn and silicate in the subarctic North Pacific plotted as a concave curve. Values of Zn* were strongly positive in the intermediate waters (26.6-27.5 sigma(theta)) of both the western and the central subarctic North Pacific. There was a distinct kink in the relationship between dissolved Zn and soluble reactive phosphorus (SRP) at the transition from shallow to intermediate water, which is similar to what has been reported for other open oceans. The high Zn: SRP ratio and high Zn* in the intermediate water suggest that intermediate water masses play an important role in the decoupling of dissolved Zn and silicate in the subarctic North Pacific, which implies that the biogeochemical processes that control dissolved Zn and silicate in the intermediate water are different from those in other oceanic regions.

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