4.5 Review

Tunable fluorescent carbon dots: synthesis progress, fluorescence origin, selective and sensitive volatile organic compounds detection

Journal

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/10408436.2020.1830750

Keywords

Tunable fluorescent carbon dots; top-down and bottom-up synthetic approaches; fluorescence quantum yield; fluorescence mechanism; selective VOCs sensors

Funding

  1. Charles University in Prague
  2. ICPF AS CR
  3. VIT University
  4. DST INSPIRE fund [DST/INSPIRE Faculty Award/2018/DST/INSPIRE/04/2018/002484]
  5. SERB [SRG/2020/000645]

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Carbon dots are emerging nanomaterials with environmental friendliness, brightness, tunable fluorescence, and low toxicity, offering potential applications in various fields. Their synthesis, fluorescence properties, and applications in sensing and recognition of volatile organic compounds have been extensively researched.
Carbon dots (C-dots) are emergent nanomaterials of carbon-based materials family and have gained significant research interest because of their environmental friendliness, brightness, tunable fluorescence, chemical inertness, low cost, simple synthetic route and availability for wide variety of starting materials. These are considered as potential competitor to conventional semiconductor quantum dots in terms of lower toxicity. It is found that their involvement in adverse fields of chemical and bio-sensing, bio-imaging, drug delivery, photocatalysis, electrocatalysis and light-emitting devices makes as an ideal and potential candidate. Interestingly they are treated as important and versatile platform for engineering multifunctional nanosensors. This review focuses on the remarkable research progress of high quality tunable fluorescent C-dots synthesis via familiar top-down and bottom-up approaches. Their fluorescence origin has been nicely demonstrated by quantum confinement effect, surface state and molecular fluorescence properties. Finally, selective and sensitive atmospheric prevailed volatile organic compounds recognition has been explained with C-dots in both solution and solid phase along with discussion on challenging and future research direction.

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