Journal
SYNTHESIS-STUTTGART
Volume 53, Issue 4, Pages 653-665Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1705951
Keywords
acyl fluorides; organofluorine compounds; fluorine; fluorination; synthetic methods
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Fonds de recherche du Quebec - Nature et technologies (FRQNT)
- OmegaChem
- Universite Laval
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This review summarizes recent advances in the preparation of acyl fluorides, including nucleophilic fluorination and radical fluorination methods, providing a reference for further research in the field of organic synthesis.
Acyl fluorides are valuable intermediates in organic synthesis. They are increasingly employed in peptide synthesis, in challenging esterification and amidation reactions or in transition-metal-catalyzed transformations. This review summarizes recent advances in their preparation. 1 Introduction 2 Nucleophilic Fluorination 2.1.-Fluoroamine Reagents 2.2 Sulfur-Based Reagents 2.3 Metal Catalysts 2.4 Phosphorus-Based Reagents 2.5 N,N'-Dicyclohexylcarbodiimide/HF center dot Pyridine 2.6 Uranium Hexafluoride 2.7 Bromine Trifluoride 3 Radical Fluorination 4 Conclusion
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