Journal
SCIENCE CHINA-MATERIALS
Volume 64, Issue 5, Pages 1105-1113Publisher
SCIENCE PRESS
DOI: 10.1007/s40843-020-1510-4
Keywords
Fe3O4; mesoporous; nanoarray; anode; Ni/Fe battery
Categories
Funding
- National Key Research and Development Program of China [2018YFA0702000]
- National Natural Science Foundation of China (NSFC)
- Beijing Natural Science Foundation [2204089]
- Fundamental Research Funds for the Central Universities
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In this study, high-performance anodes for rechargeable Ni/Fe batteries were prepared using mesoporous Fe3O4@C nanoarrays as the electrode material. The unique mesoporous nanoarray architecture provided larger specific surface area, faster charge/mass transport, and higher utilization of Fe3O4, leading to ultrahigh specific capacity and superior stability in aqueous electrolyte. When combined with hierarchical mesoporous NiO nanoarray cathodes, the optimized rechargeable Ni/Fe battery showed high energy/power densities and excellent cyclability.
Rechargeable aqueous batteries with high power density and energy density are highly desired for electro-chemical energy storage. Despite the recent reports of various cathode materials with ultrahigh pseudocapacitance exceeding 3000 F g(-1) (or 800 mA h g(-1)), the development of anode materials is relatively insufficient, which limits the whole performance of the devices far from practical applications. Herein, we report the preparation of mesoporous Fe3O4@C nanoarrays as high-performance anode for rechargeable Ni/Fe battery by a self-generated sacrificial template method. ZnO/Fe3O4 composite was first synthesized by a co-deposition process, and ZnO was subsequently removed by alkali etching to construct the mesoporous structure. A thin carbon film was introduced onto the surface of the electrode by the carbonization of glucose to increase the structural stability of the electrode. The unique mesoporous nanoarray architecture endows the electrode with larger specific surface area, faster charge/mass transport and higher utilization of Fe3O4, which shows an ultrahigh specific capacity (292.4 mA h g(-1) at a current density of 5 mA cm(-2)) and superior stability in aqueous electrolyte (capacitance retention of 90.8% after 5000 cycles). After assembled with hierarchical mesoporous NiO nanoarray as a cathode, an optimized rechargeable Ni/Fe battery with double mesoporous nanoarray electrodes was fabricated, which provided high energy/power densities (213.3 W h kg (-1) at 0.658 kW kg(-1) and 20.7 kW kg(-1) at 113.9 W h kg(-1), based on the total mass of the active materials) in the potential window of 1.5 V with excellent cyclability (81.7% retention after 5000 charge/discharge cycles).
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