Mott Switching and Structural Transition in the Metal Phase of VO2 Nanodomain

VO2 undergoes the insulator-metal transition (IMT) and monoclinic-rutile structural phase transition (SPT) near 67 degrees C. The IMT switching has many applications. However, there is an unresolved issue whether the IMT is a Mott transition or a Peierls transition. This complication is caused by metal and insulator coexistence, which is an inherent property of the IMT region. Thus, the acquired data in the IMT region are averaged over the two phases in many experiments. We overcome the issue by probing the electronic state of the monoclinic structure and by introducing a model that accounts for the coexisting phases. We reveal the Mott IMT in the nondistorted monoclinic nanodomain between 55 and 63 degrees C and the distortion-assisted SPT above 60 degrees C.

Automated summary

VO2 undergoes insulator-metal transition and structural phase transition near 67 degrees C. The unresolved issue lies in whether this transition is a Mott transition or a Peierls transition due to the coexistence of metal and insulator. By probing the electronic state of the monoclinic structure and introducing a model, researchers have revealed different transition processes at varying temperatures.