Microstructural and spectroscopic analysis in non-uniform Y2O3 ceramics fabricated by spark plasma sintering

In Y2O3 ceramics densified at 1000 degrees C by spark plasma sintering (SPS), non-uniform sintering behavior of grains and pores occurred for a heating rate of 20 degrees C/min. The sintered Y2O3 was translucent at the periphery but white and opaque at the center. According to microstructural analysis, the non-uniform sintering was caused by rapid grain growth and pore coarsening at the center. Under complicated electric and magnetic fields during SPS, an assumption of the movement of defects toward the center enables to explain the microstructural nonuniformity. For the non-uniform sintering behavior, spectroscopic analysis was used to investigate the introduced impurities (C, H, O) and by-products (carbonates). In the spectroscopic analysis, the peaks located at 2555, 2950, and 3560 cm(-1) (O-H stretching band of H2O) were weakly detected for low heating rates but clearly detected for high heating rates. This is because H2O adsorbed to the initial Y2O3 powder was not sufficiently removed and was trapped during rapid densification at high heating rates. Due to the carbon-rich environment during SPS, carbonate was formed by the reaction of carbon with -OH. Most carbons were detected as a C-O peak, indicating that a reaction of carbon with -OH occurred. (C) 2021 The Ceramic Society of Japan. All rights reserved.

Automated summary

In Y2O3 ceramics densified at 1000 degrees C by spark plasma sintering (SPS) with a heating rate of 20 degrees C/min, non-uniform sintering behavior of grains and pores was observed. The non-uniform sintering was attributed to rapid grain growth and pore coarsening at the center, possibly due to the movement of defects towards the center under electric and magnetic fields during SPS. Spectroscopic analysis revealed the presence of introduced impurities and by-products, with water peaks being more clearly detected at high heating rates due to insufficient removal of adsorbed water during rapid densification. Carbonates were formed by the reaction of carbon with -OH, detected mostly as a C-O peak in the spectroscopic analysis.