Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 1, Pages 81-84Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07305a
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Funding
- JSPS KAKENHI [JP26220803, JP17H06450, JP18J22096]
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This study presents a Cu-catalyzed O-alkylation of phenol derivatives using alkylsilyl peroxides as alkyl radical precursors. The reaction proceeds smoothly under mild conditions and the use of two different ligands with a Cu catalyst provides a wide range of products. Mechanistic studies suggest that the reaction proceeds via a radical mechanism.
A Cu-catalyzed O-alkylation of phenol derivatives using alkylsilyl peroxides as alkyl radical precursors is described. The reaction proceeds smoothly under mild reaction conditions and the use of two different ligands with a Cu catalyst provides a wide range of products. A mechanistic study suggested that the reaction proceeds via a radical mechanism.
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