4.7 Article

Light-mediated chiroptical switching of an achiral foldamer host in presence of a carbohydrate guest

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 1, Pages 93-96

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06484j

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A study found that a carbohydrate guest can induce opposite handedness when binding to a foldamer containing a diarylethene, enabling chiroptical switching of an achiral host.
A photoresponsive diarylethene was incorporated in an achiral helical foldamer container. A carbohydrate guest was found to induce opposite handedness upon binding to the open and closed forms of the diarylethene-containing foldamer, thus enabling chiroptical switching of an achiral host mediated by a chiral guest.

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