Journal
ACS MATERIALS LETTERS
Volume 3, Issue 1, Pages 100-109Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsmaterialslett.0c00520
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Funding
- U.S. Department of Energy through LDRD Award [DE-AC52-07NA27344, 19-SI-005]
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A new Cu2O/CuS composite catalyst with excellent activity for formate generation through CO2RR has been reported, achieving high faradaic efficiency and current density, along with long-term stability. The catalytic selectivity and stability for formate production outperform other Cu, CuS, and Cu2O catalysts.
Formate is an important value-added chemical that can be produced via electrochemical CO2 reduction reactions (CO2RR). Cu2O-based catalysts have previously demonstrated decent activity for formate generation; however, they often suffer from poor electrochemical stability under reductive conditions. Here, we report a new Cu2O/CuS composite catalyst that simultaneously achieves an excellent faradaic efficiency of 67.6% and a large partial current density of 15.3 mA/cm(2) at -0.9 V vs RHE for formate. Importantly, it maintains an average faradaic efficiency of 62.9% for at least 30 h at the same potential. The catalytic selectivity and stability for formate production outperform other Cu, CuS, and Cu2O catalysts.
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