4.7 Article

Why copper may be able to corrode in pure water

Journal

CORROSION SCIENCE
Volume 93, Issue -, Pages 327-329

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2015.01.002

Keywords

Copper; Hydrogen absorption; Oxidation

Funding

  1. Swedish Radiation Safety Authority

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In exposure of copper to water molecules there will be relatively strong bonds (reversible traps) between copper and hydrogen. One copper-hydrogen bond corresponds to the thermal energy of a temperature of approximately 250 degrees C and this explains an unusual temperature influence on hydrogen uptake in the metal and in corrosion of copper in pure water-vapour without O-2. This unusual temperature influence is exemplified in exposure of copper at 180 degrees C and 500 degrees C where Cu corrodes more at 180 degrees C than at 500 degrees C. (C) 2015 Elsevier Ltd. All rights reserved.

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