An ultra-long life aqueous full K-ion battery

Aqueous full K-ion batteries (AFKIBs) featuring high safety, low cost, and environmental friendliness represent the future of advanced energy storage technologies. However, current AFKIB systems are still in need of suitable electrolytes and electrode materials, not to mention durability. Here, we report a rocking-chair type aqueous full K-ion system with KTi2(PO4)(3)/C crystalline nanoparticles as the anode material with near zero-strain, iron hexacyanoferrate as the cathode, and 21 m KCF3SO3 as a water-in-salt electrolyte. Benefitting from the fast reaction kinetics and high structural stability of KTi2(PO4)(3)/C, the full battery achieves a high capacity retention of 96.7% over 30 000 cycles, excellent rate performance with full charge and discharge in 1 minute, and a high energy density of 47.3 W h kg(-1). Demonstration of the performance of this AFKIB system expands the avenues of exploration for large-scale energy storage.

Automated summary

This study presents a rocking-chair type aqueous full K-ion system with high capacity retention, excellent rate performance, and high energy density, demonstrating fast reaction kinetics and high structural stability of the materials used. The system represents the future of advanced energy storage technologies, utilizing KTi2(PO4)(3)/C as the anode material, iron hexacyanoferrate as the cathode, and 21 m KCF3SO3 as the water-in-salt electrolyte.