4.8 Review

The rise of metal-organic polyhedra

Journal

CHEMICAL SOCIETY REVIEWS
Volume 50, Issue 1, Pages 528-555

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00443j

Keywords

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Funding

  1. National Research Foundation of Korea [NRF-2016R1A5A1009405, 2020R1A2C3008226]
  2. Korea Environment Industry & Technology Institute (KEITI) through Public Technology Program based on Environmental Policy Program - Korea Ministry of Environment (MOE) [2018000210002]
  3. National Research Foundation of Korea [2020R1A2C3008226] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Metal-organic polyhedra, as a type of metal-organic material, are emerging porous platforms used in energy and bio-related sciences, but have been less explored compared to their framework counterparts. This review covers the topologies and classification of metal-organic polyhedra and provides suggestions for future directions in this rapidly growing field that may benefit synthetic chemists.
Metal-organic polyhedra are a member of metal-organic materials, and are together with metal-organic frameworks utilized as emerging porous platforms for numerous applications in energy- and bio-related sciences. However, metal-organic polyhedra have been significantly underexplored, unlike their metal-organic framework counterparts. In this review, we will cover the topologies and the classification of metal-organic polyhedra and share several suggestions, which might be useful to synthetic chemists regarding the future directions in this rapid-growing field.

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